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center;"></p><p>單體雜質對聚丙烯酰胺過濾性的影響:</p><p>在丙烯酰胺的生產中，一些有機雜質隨著副反應被引入，這些雜質在丙烯酰胺聚合中起支化作用，產生大量非線性聚合物，增加了過濾系數。與生物法相比，化學催化水合法副產物較多，尤其是生產不穩定時，AM產品中有機雜質含量較高，直接影響聚丙烯酰胺產品的過濾性能。</p><p>鏈轉移劑對聚丙烯酰胺過濾性的影響:<br/></p><p>鏈轉移劑雖然能很好的控制產品的過濾性，但要提高聚丙烯酰胺的相對分子量，就必須降低其用量，但不能保證過濾性，二者之間的矛盾尤為突出。<br/></p><p>水解度對聚丙烯酰胺過濾性的影響:<br/></p><p>聚丙烯酰胺水解成部分水解的聚合物后，由于羧酸酯基團之間的靜電排斥作用，溶液中大分子線圈的延伸度會隨著水解度的增加而增加。當水解度為40%時，延伸度會更大，超過50%后，由于鹽敏效應的增強，延伸度會逐漸減小。<br/></p><p>干燥溫度和時間對聚丙烯酰胺過濾性的影響:<br/></p><p>聚丙烯酰胺膠體干燥過程中可能發生殘留單體的熱聚合。由于殘留引發劑的引發，主鏈或側基的熱分解和再聚合，分子間或分子內的亞胺化反應，分子鏈會斷裂和架橋。這些變化使得產品的相對分子量低，不溶物多，過濾比過高。這就要求聚丙烯酰胺的干燥溫度不能太高(60)，不能局部過熱。生產中使用的流化床干燥方法是科學的，但有時干燥溫度過高、過長、局部溫度過高。</p><p> </p></span></p> <div class="prenext"> <div class="yunu-infocontent-return"> 本文標簽：</div> <span class="pre"><b>上一篇：</b><a href='http://www.521qzone.cn/jishu/776.html'>絮凝劑在凈水過程中的作用和使用方法</a></span> <span class="next"><b>下一篇：</b><a href='http://www.521qzone.cn/jishu/778.html'>絮凝劑使用后在初沉池沒有沉淀怎么辦？</a></span> <div class="clearfix"></div> </div> <div class="clearfix"></div> <div 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